Composition for forming a film on keratin fibres

ABSTRACT

A composition for providing a film on keratin fibres, the composition comprising: a film-forming aminosilicone polymer; a silicone resin; an ether of a water-soluble polyhydric alcohol; a thickening system comprising a deposition enhancer and a thickening polymer; one or more coloured materials or one or more pigments; water; 2-phenoxyethanol and/or phenylmethanol; wherein the composition is substantially free of esters of parahydroxybenzoic acid; and wherein the composition is substantially free of isothiazolinone compounds. Also, associated methods, kits and uses.

FIELD OF THE INVENTION

The present invention relates to the field of cosmetics, particularlyhair cosmetics, and relates to compositions for providing a film onkeratin fibres.

BACKGROUND OF THE INVENTION

Semi-permanent treatments to human keratin fibres are well known in theart. Of particular note are semi-permanent treatments that alter thecolour appearance of the hair or provide other coloured or reflectiveproperties via the use of glitter or particles. For example, direct dyescolour the hair in a semi-permanent fashion by adhering colouredmolecules to the keratin fibres. The dye can be later washed out. Hairchalks are powder-based or powdery products—typically provided in ablusher-style ‘compact’ or in pen format—that enable the user to applypigments and/or coloured particles to the hair.

A drawback of the known technology in this area is low adherence of thepigment or coloured material to the keratin fibres—it is a seriousconsumer concern that such products can make your clothes and/orbathroom dirty and/or stained. Furthermore, such pigment or colouredmaterial can migrate to the skin on your neck, shoulders and face andcause unsightly marks. Moreover, consumers wish to be able to apply.Chalk products typically provide a matt look, which may not be desiredby all consumers and would not provide a vibrant, shiny look where theconsumer desires this.

Thus there is a need for compositions and methods that provide moredurable means to adhere pigments and/or coloured/shiny material tokeratin fibres. In particular, there is a need for providing improveddeposition of these particles. Furthermore, there is a need forproviding a composition that is able to deposit a wide variety ofparticles—whether pigments, glitter or other coloured material. Inaddition, there is a need for such a composition that can be easilyapplied and distributed over the hair—for example does not result inclumping of the composition, or any kind of gluey-ness or gunky-ness ofany kind on the head of hair. Indeed, there is a need for a more naturallook to be provided by such means.

Teboul WO2014/001391A1, which published on 3 Jan. 2014 relates to a“process for dyeing keratin fibres, in particular the hair, whichconsists in applying to the keratin fibres: —at least one coat of atleast a first composition (i) comprising at least one hydrophobicfilm-forming polymer, at least one volatile solvent and at least onepigment, and then, after drying the said coat, at least a second coat ofat least a second composition (ii) comprising at least one hydrophobicfilm-forming polymer, at least one volatile solvent and at least onepigment . . . ”. Teboul does not disclose an aminosilicone polymercomprising an amino side chain. Maillefer et al in EP2090295A1, whichpublished on 19 Aug. 2009, mentions pigments in § 127, but in thecontext of a “method and composition for improving the drying time ofhair”. For example, there is no teaching in Maillefer et al ondeposition enhancers. Calaco et al in WO2013/085577A2, which publishedon 13 Jun. 2013, mentions compositions and methods are disclosed forimparting a long-wearing color to keratin fibers. However, Calaco et alalso does not teach deposition enhancement.

None of the prior art teach or provide solutions that fulfil all theconsumers' needs.

SUMMARY OF THE INVENTION

A composition for providing a film on keratin fibres, is provided andcomprised:

-   -   (a) an aminosilicone polymer, wherein the aminosilicone polymer        comprises amino sidechains, and wherein the aminosilicone        polymer as a weight average molecular weight of from 10,000        Dalton to 60,000 Dalton;    -   (b) a silicone resin;    -   (c) an ether of a water-soluble polyhydric alcohol;    -   (d) a thickening system comprising:        -   a deposition enhancer, wherein the deposition enhancer is a            hydrophilic and non-ionic polymer, and wherein the            deposition enhancer has a weight average molecular weight of            at least 300,000 Dalton to 7,500,000 Dalton;        -   a thickening polymer, wherein the thickening polymer has a            weight average molecular weight of at least 10,000 Dalton,            and wherein the thickening polymer is a cationic thickening            polymer or is a non-ionic thickening polymer;    -   (e) one or more coloured materials or one or more pigments;    -   (f) water;    -   (g) 2-phenoxyethanol and/or phenylmethanol;    -   wherein the composition is substantially free of esters of        parahydroxybenzoic acid; and wherein the composition is        substantially free of isothiazolinone compounds. The composition        may be substantially free of compounds causing precipitation of        any component of the composition when the composition is in        aqueous solution at pH 5 and at 25° C.

A method for providing a film comprising one or more pigments or one ormore coloured materials onto keratin fibres, is provided and comprisedapplying the composition as set out herein above onto keratin fibres andallowing the keratin fibres to dry or drying them.

A kit is provided and comprised:

-   -   the composition as set out herein above;    -   an applicator.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1: Rheological measurements of compositions according to thepresent invention. X=strain (%) and Y=tangent delta.

DETAILED DESCRIPTION OF THE INVENTION Definitions and General

In this document, including in all embodiments of all aspects of thepresent invention, the following definitions apply unless specificallystated otherwise. All percentages are by weight (w/w) of the totalcomposition. “wt %” means percentage by weight. All ratios are weightratios. References to ‘parts’ e.g. a mixture of 1 part X and 3 parts Y,is a ratio by weight. “QS” or “QSP” means sufficient quantity for 100%or for 100 g.+/− indicates the standard deviation. All ranges areinclusive and combinable. The number of significant digits conveysneither a limitation on the indicated amounts nor on the accuracy of themeasurements. All numerical amounts are understood to be modified by theword “about”. All measurements are understood to be made at 23° C. andat ambient conditions, where “ambient conditions” means at 1 atmosphere(atm) of pressure and at 50% relative humidity. “Relative humidity”refers to the ratio (stated as a percent) of the moisture content of aircompared to the saturated moisture level at the same temperature andpressure. Relative humidity can be measured with a hygrometer, inparticular with a probe hygrometer from VWR® International. Herein “min”means “minute” or “minutes”. Herein “mol” means mole. Herein “g”following a number means “gram” or “grams”. All amounts as they pertainto listed ingredients are based on the active level (‘solids’) and donot include carriers or by-products that may be included in commerciallyavailable materials. Herein, “comprising” means that other steps andother ingredients can be in addition. “Comprising” encompasses the terms“consisting of” and “consisting essentially of” The compositions,formulations, methods, uses, kits, and processes of the presentinvention can comprise, consist of, and consist essentially of theelements and limitations of the invention described herein, as well asany of the additional or optional ingredients, components, steps, orlimitations described herein. Embodiments and aspects described hereinmay comprise or be combinable with elements, features or components ofother embodiments and/or aspects despite not being expressly exemplifiedin combination, unless an incompatibility is stated. “In at least oneembodiment” means that one or more embodiments, optionally allembodiments or a large subset of embodiments, of the present inventionhas/have the subsequently described feature. Where amount ranges aregiven, these are to be understood as being the total amount of saidingredient in the composition, or where more than one species fallwithin the scope of the ingredient definition, the total amount of allingredients fitting that definition, in the composition. For example, ifthe composition comprises from 1% to 5% fatty alcohol, then acomposition comprising 2% stearyl alcohol and 1% cetyl alcohol (and noother fatty alcohol), would fall within this scope.

The term “molecular weight” or “M.Wt.” as used herein refers to theweight average molecular weight unless otherwise stated. The weightaverage molecular weight may be measured by gel permeationchromatography.

“Viscosity” is measured at 23° C. using a HAAKE Rotation Viscometer VT550 with cooling/heating vessel and sensor systems according to DIN53019 at a shear rate of 12.9 s⁻¹.

“Water-soluble” refers to any material that is sufficiently soluble inwater to form a clear solution to the naked eye at a concentration of0.1% by weight of the material in water at 23° C. The term“water-insoluble” refers to any material that is not “water-soluble”.

“Dry” or “substantially dry” means comprising less than 5%, less than 3%or, less than 2%, less than 1%, or about 0% of any compound orcomposition being in liquid form when measured at 23° C. at ambientconditions. Such compounds or compositions being in liquid form includewater, oils, organic solvents and other wetting agents. “Anhydrous”means that the composition comprises less than 5%, less than 3% or, lessthan 2%, less than 1%, or about 0% water by total weight of thecomposition.

“Substantially free from” or “substantially free of” means less than 1%,or less than 0.8%, or less than 0.5%, or less than 0.3%, or about 0%, bytotal weight of the composition or formulation.

“Volatile” means materials that are liquid under ambient conditions andwhich have a measurable vapour pressure at 25° C. These materials have avapour pressure greater than 1.3 Pa, or from 26.7 Pa to 5 kPa, and astandard boiling point less than 250° C., or less than 235° C., or lessthan 150° C. “Standard boiling point” is as defined by the InternationalUnion of Pure and Applied Chemistry (IUPAC).

“Hair” means mammalian keratin fibres including scalp hair, facial hairand body hair. It includes such hair still being attached to a livingsubject and also hair that has been removed therefrom such as hairswatches and hair on a doll/mannequin. “Hair” means human hair only.“Hair shaft” or “hair fibre” means an individual hair strand and may beused interchangeably with the term “hair.”

“Proximal to the scalp” means that portion of an extended, orsubstantially straightened, hair shaft that is closer in distance to thescalp than to the end of the hair. Thus, 50% of the hair fibre lengthwould be considered proximal to the scalp, and 50% of the hair fibrewould be distal to the scalp. “z cm proximal to the scalp” means adistance “z” along the hair, with one endpoint being on or directlyadjacent to the scalp, and the second endpoint being measured “z”centimetres along the length of the extended or substantiallystraightened hair.

“Cosmetically acceptable” means that the compositions, formulations orcomponents described are suitable for use in contact with humankeratinous tissue without undue toxicity, incompatibility, instability,allergic response, and the like. All compositions and formulationsdescribed herein which have the purpose of being directly applied tokeratinous tissue are limited to those being cosmetically acceptable.

“Derivatives” includes but is not limited to, amide, ether, ester,amino, carboxyl, acetyl, acid, salt and/or alcohol derivatives of agiven compound. “Derivatives thereof” means the amide, ether, ester,amino, carboxyl, acetyl, acid, salt and alcohol derivatives.

“Monomer” means a discrete, non-polymerised chemical moiety capable ofundergoing polymerisation in the presence of an initiator or anysuitable reaction that creates a macromolecule e.g. such aspolycondensation, polyaddition, anionic or cationic polymerization.“Unit” means a monomer that has already been polymerised i.e. is part ofa polymer.

“Polymer” means a chemical formed from the polymerisation of two or moremonomers. The term “polymer” shall include all materials made by thepolymerisation of monomers as well as natural polymers. Polymers madefrom only one type of monomer are called homopolymers. Herein, a polymercomprises at least two monomers. Polymers made from two or moredifferent types of monomers are called copolymers. The distribution ofthe different monomers can be random, alternating or block-wise (i.e.block copolymer). The term “polymer” used herein includes any type ofpolymer including homopolymers and copolymers.

“Kit” means a package comprising a plurality of components. “Kit” may bereferred to as “kit-of-parts”. An example of a kit is, for example, afirst composition and a separately packaged second composition andoptionally application instructions.

“Hairstyling polymer” means a hair-fixing polymer which forms a film ona surface i.e. a film-forming polymer. ‘Hairstyling polymer’ and‘film-forming polymer’ are used interchangeably in the art. In thecontext of hair science, this surface is the surface of individual hairfibres or a plurality thereof. The hairstyling polymer causes the hairfibres to be glued together to build welds, which are effectivelycrosslinks that provide the hold benefit. In concert, these welds form a‘hairnet’ to provide hair hold and volume benefits to the consumer. Whenthe net of welds is effectively formed, the hold and volume benefits canlast all day and offer good resistance to environmental humidity.

Theory Behind and Advantages of the Present Invention

The inventors provide herein a composition for providing a film onkeratin fibres, more particularly a composition for providing a colouredfilm on keratin fibres. Indeed, the combination of film-formingaminosilicone polymer, silicone resin, solvent and selected thickeningsystem results in a film on keratin fibres, particularly human headhair, that is sufficiently durable that it does not quickly rub offwhilst on the keratin fibres, for example on the hands, clothes etc ofthe consumer, nor does it provide bad hair feel, such as lumpiness, norabrasiveness, nor weigh down the hair reducing the head of hair volume,nor unsightly globules.

Indeed, the film-forming aminosilicone polymer and silicone resin enablethe forming of a very thin, dry film, which tightly binds any colouredmaterial and/or pigment onto the hair fibres in a durable fashion. Theaminosilicone polymer and silicone resin provides an excellent film viaa dehydration mechanism.

The selected thickening system can help to prevent dripping of thecomposition by inhibiting capillary action, which would otherwisequickly draw the composition down the fibres and onto the floor and/orclothes of the user. Nevertheless, the thickening system, particularlythe combination of thickening polymer and deposition enhancer, provide anon-dripping composition that adheres well to keratin fibres withoutgenerating a sticky feel. Moreover, the thickening system does notdetract from the ability of the film-forming aminosilicone polymer andsilicone resin to provide the thin, dry film.

In particular, the present invention overcomes the drawbacksdemonstrated by previous developments in this area in that it is able toprovide subtle hair effects that can be employed by a much wider varietyof end-consumers in a wider variety of life contexts. In other words,the effects provided by the present invention are not limited to highlyvibrant and dazzling hair effects that are often used prior to visitinga disco or nightclub, but also provides chic hair looks that areacceptable in a business context and also not too overpowering foreveryday hair looks.

Indeed, the selected combination of features—the combination offilm-forming aminosilicone polymer, silicone resin, solvent and selectedthickening system—provides an excellent support system for colouredmaterial and/or pigments, which can provide the desired effects to thehair, such as glitteriness, colour, shininess etc. Said colouredmaterial and/or pigments may be provided separately from the compositionchassis such that the consumer and/or stylist can select the exact theexact type of pigment and/or coloured material desired.

Composition of the First Aspect

The composition as set out herein above is for providing a film onkeratin fibres. The composition may be for providing a film comprisingpigment or coloured material on keratin fibres. The film may be adurable film.

The composition may be substantially free of compounds causingprecipitation of any component of the composition when the compositionis in aqueous solution at pH 5 and at 23° C. When the compositiontypically comprises a film-forming aminosilicone polymer, a MQ resin, athickening system comprising a deposition enhancer and a thickeningpolymer, and a solvent, the pH of the composition may be between 4 and6, preferably between 4.5 and 5.5. Examples of compounds causingprecipitation of any component of the composition when the compositionis in aqueous solution at pH 5 and at 23° C. may be a basic solvent, orionic compounds or compounds that are cationic from pH 4 to 6,preferably from pH 5 to 6 or compounds having a relative ionic strength.

Indeed, precipitation of any component of the present composition wouldhave negative side effects on the efficacy of the presentinvention—particularly in terms of hair feel. Indeed, with the exclusionof the pigment and/or coloured material that is herein intended to beimmobilised on hair, other residues on hair are not accepted by theconsumer. For example, precipitation of the film-forming aminosiliconepolymer and/or silicone resin would detract from their ability to form afilm on the hair fibres and would form residues on hair. The compositionmay be substantially free of any further ionic compounds. Thecomposition may be substantially free of any compounds that are cationicat pH 4.0 to 5.0.

Aminosilicone & Silicone Resin

The composition comprises a film-forming aminosilicone polymer, whereinthe aminosilicone polymer comprises amino side chains, and wherein theaminosilicone polymer has a weight average molecular weight of from10,000 Dalton to 60,000 Dalton. “Sidechain” (aka “side chain”) in thecontext of a silicone refers to a group being not part of the siliconebackbone nor only present on at least one terminus of the siliconebackbone. “Terminal aminosilicone” as defined herein means siliconecomprising one or more amino groups at one or both ends of the siliconebackbone Aminosilicone polymers having amino side chains are sometimesreferred to as silicone compounds comprising pendant amino groups. Theaminosilicone polymer may be not a terminal aminosilicone. Thecomposition may be substantially free of silicones having terminal aminogroups.

The aminosilicone polymer is a film-forming aminosilicone polymer. Theaminosilicone polymer may be a polydimethylsiloxane having graft aminogroups.

The aminosilicone polymer may have a weight average molecular weight offrom 15,000 Dalton to 50,000 Dalton, or from 20,000 Dalton to 40,000Dalton.

The aminosilicone polymer may be a polydimethylsiloxane polymer havingpendent (graft) amino groups. The aminosilicone polymer may conform tothe formula:

in which x′ and y′ are integers such that the weight average molecularweight is between 10,000 Dalton and 60,000 Dalton. The endcaps may bemethoxy rather than hydroxyl as pictured in the above formula.

The aminosilicone polymer may be a polydimethylsiloxane polymer having asidechain with from 3 to 8 carbon atoms. The sidechain may comprise, orpreferably may consist of carbon, hydrogen and nitrogen atoms. Theaminosilicone polymer may be a polydimethylsiloxane polymer having anaminoethyl aminopropyl sidechain.

The aminosilicone polymer may conform to the formula:

in which n and m are integers such that the weight average molecularweight is between 10,000 Dalton and 60,000 Dalton, R₁ and R₃ areindependently selected from —OH or —OCH₃; R₂ is H or a C₁ to C₃ alkyl,or methyl or H, preferably methyl. “n” may be on average from 1 to 50,or from 5 to 20, or from 6 to 10, or from 8 to 9, and “m” may be onaverage from 120 to 300, or from 150 to 200. “n” may be on average from5 to 8, “m” may be on average from 150 to 180, R₁ and R₃ may be bothmethyl, and R₃ is —OCH₃.

The aminosilicone polymer may have an amine number of from 0.1 meq/g to3 meq/g, or from 0.7 meq/g to 2.5 meq/g, or from 0.6 meq/g to 1 meq/g.

Suitable example aminosilicone polymers can be found in the followingpatent documents, which are incorporated herein by reference: DecosterU.S. Pat. No. 6,451,747B1 col. 17, 11.4-27; Hughes U.S. Pat. No.5,567,428 col. 13, 11.40-56; Gawtrey et al US2004/0010863A1, § 0016 to §0039; Mahr et al US2006/0041026A1.

The composition may comprise from 1% to 15%, or from 1.5% to 5% of theaminosilicone polymer. The viscosity of the aminosilicone polymer may befrom 10 to 100,000 mPa·s, or from 100 to 10,000 mPa·s.

The composition comprises a silicone resin. Silicone resins are known inthe art. The silicone resin may be a film-forming polymer. The siliconeresin may be an MQ resin. “M” stands for Me₃SiO and “Q” stands for SiO₄.The MQ resin may have an M:Q molar ratio of from 0.5:1.0 to 1.5:1.0. Theweight average molecular weight of the resin may be from 1000 Daltons to10,000 Daltons. The MQ resin may contain at least 80 mol. %, or at least95 mol. %, of units of the general formulae below:R⁷ ₃SiO_(1/2)SiO_(4/2)in which R⁷ is C₁₋₄₀ alkyl, H, —OR or —OH radicals. The ratio of theunits of the general formulae may be from 0.5 to 2.0, or from 0.5 to1.5. The not more than 3% by weight, or not more than 2.5% by weight, ofthe radicals R⁷ may be —OR and —OH.

The remaining units of the MQ silicone resin may be units of thefollowing general formulae:R⁷ ₂SiO_(2/2)R⁷SiO_(3/2)in which R⁷ is C₁₋₄₀ alkyl, H, —OR or —OH radicals.

R⁷ may be C₁₋₄₀ alkyl that is optionally halogen-substituted, linear,cyclic, branched, aromatic, saturated or unsaturated. R⁷ may be an alkylgroup having C₁₋₆ carbon atoms, or a phenyl radical. The halogensubstituents may be selected from fluorine and chlorine. R⁷ may beselected from methyl, ethyl, phenyl and H. The composition may comprisefrom 0.1% to 10%, or from 1% to 5%, or from 2% to 4% of the MQ resin.

MQ resins are available from Wacker-Chemie AG, D-81737 Munchen, Germany.For example, MQ-RESIN POWDER 803 TF is a co-hydrolysis product oftetraalkoxy silane (Q unit) and trimethyl-ethoxy silane (M unit) and canbe seen as a three dimensional network of polysilicic acid units whichare endblocked with trimethylsilyl groups. Some residual ethoxy andhydroxy functions are present. MQ resins are also available from DowCorning. For example, Dow Corning® MQ-1640 Flake Resin is a combinationof MQ and T propyl silicone resin and has the INCI name: Trimethylsiloxysilicate (and) Polypropyl silsesquioxane.

The composition comprises an ether of a water-soluble polyhydricalcohol. The ether of a water-soluble polyhydric alcohol has theadvantage that it is able to prevent the aminosilicone and the siliconeresin from forming a complex. The ether of a water-soluble polyhydricalcohol may be a non-polymeric, amphiphilic compound. Indeed, theaminosilicone comprises amino side chains, which lend hydrophiliccharacter to the aminosilicone, and the silicone resin typically ishydrophobic in nature. Thus where the ether of a water-solublepolyhydric alcohol has amphiphilic chemistry it can interact with boththe aminosilicone and the silicone resin and keep them from clumping,and also from precipitating. The composition may comprise an ether of awater-soluble polyhydric alcohol, wherein the ether of a water-solublepolyhydric alcohol may be selected from the group consisting ofdiethyleneglycol monobutylether, ethylene glycol monohexyl ether, and amixture of diethyleneglycol monobutylether and ethylene glycol monohexylether. The composition may comprise from 0.01% to 20%, or from 0.1% to10%, or from 0.5% to 5%, or from 1.0% to 5%, or from 2% to 5% of theether of a water-soluble polyhydric alcohol.

A suitable product for use in the present invention is available underthe trade mark Wacker®/BELSIL ADM 8301 E by the company Wacker-ChemieAG, D-81737 Munchen, Germany. This product contains from 10% to 20% ofpoly[3-((2-aminoethyl)amino)propyl]methyl(dimethyl)siloxane,hydroxyterminated, which is an aminosilicone. It also contains from 0.1%to 0.2% octamethylcyclotetrasiloxane and from 1% to 5% of an MQ siliconeresin. The product also contains from 1% to 3% ethylene glycol monohexylether and from 5% to 10% diethyleneglycol monobutylether. Said productis described in US2006/0041026A1 which is incorporated herein byreference. A similar product is Wacker® HC303 also from Wacker-ChemieAG.

Thickening System

The composition comprises a thickening system. The thickening systemcomprises a deposition enhancer and a thickening polymer. Thecomposition may comprise from 0.5% to 2% of the thickening system.

The thickening system comprises a deposition enhancer. The depositionenhancer is a hydrophilic and non-ionic polymer, and wherein thedeposition enhancer has a weight average molecular weight of from700,000 Dalton to 3,000,000 Dalton. The deposition enhancer is usefulfor aiding the deposition of the aminosilicone and silicone resin aswell as any pigment and/or coloured material on to the hair fibre. Inparticular, the deposition enhancer has the advantage that moreaminosilicone and silicone resin as well as any pigment and/or colouredmaterial stays on the hair fibre rather than dripping or sliding off thehair fibre. Indeed, in view of the physical structure of a head of hairi.e. a plurality of fibres that are close proximity to one another,capillary action plays a role with regards to fluids on hair. Hence, thedeposition enhancer is useful for preventing the capillary action fromstripping the aminosilicone, silicone resin and any pigment and/orcoloured material from the hair.

The composition may comprise from 0.01% to 5% of the depositionenhancer. The composition may comprise from 0.05% to 4%, or from 0.075%to 3.5%, or from 0.1% to 3%, or from 0.1% to 2%, or from 0.15% to 1% ofthe deposition enhancer.

The deposition enhancer may conform to the formula H(OCH₂CH₂)_(n)OHwherein n has an average value of from 20,000 to 50,000. The depositionenhancer may conforms to the formula H(OCH₂CH₂)_(n)OH wherein n has anaverage value of from 40,000 to 50,000. The composition may comprisefrom 0.01% to 5% of the deposition enhancer. The composition maycomprise from 0.05% to 4%, or from 0.075% to 3.5%, or from 0.1% to 3%,or from 0.1% to 2%, or from 0.15% to 1% of the deposition enhancer,wherein the deposition enhancer may conform to the formulaH(OCH₂CH₂)_(n)OH wherein n has an average value of from 40,000 to50,000.

The deposition enhancer may have a weight average molecular weight offrom 1,000,000 Dalton to 2,500,000 Dalton.

Useful deposition enhancers are available from Dow under their POLYOXbrand. In particular, POLYOX WSR N-60K is PEG-45M i.e. formulaH(OCH₂CH₂)_(n)OH wherein n is an integer and where n has an averagevalue of 45,000. PEG-45M has a weight average molecular weight of2,000,000 Dalton. Also useful is POLYOX WSR N-12K, which is PEG-23M i.e.formula H(OCH₂CH₂)_(n)OH wherein n is an integer where n has an averagevalue of 23,000. PEG-23M has a weight average molecular weight of1,000,000 Dalton. Also useful is POLYOX WSR-1105, which has a weightaverage molecular weight of 900,000 Dalton.

The thickening system comprises a thickening polymer. The thickeningpolymer has a weight average molecular weight of at least 10,000 Dalton.The thickening polymer is a cationic thickening polymer or is anon-ionic thickening polymer. The composition may comprise from 0.01% to5% of the thickening polymer. The composition may comprise from 0.1%, orfrom 0.2%, or from 0.3%, or from 0.4, or from 0.5%, or from 0.6%, orfrom 0.7%, or from 0.8%, or from 0.9% to 5%, or to 4.5%, or to 4%, or to3.5%, or to 3%, or to 2.5%, or to 2%, or to 1.5% of the thickeningpolymer. The thickening polymer may be a non-ionic thickening polymer.

The thickening polymer may be a polysaccharide. The thickening polymermay be a polysaccharide and the polysaccharide is selected from thegroup consisting of hydroxyethylcellulose, hydroxypropylcellulose,starch compounds, xanthan gum, carrageenans, and mixtures thereof. Thethickening polymer may be a heteropolysaccharide. The totalpolysaccharide content present in the composition may be from 0.2% to5%, or from 0.5% to 4%. Suitable polysaccharides andheteropolysaccharides include starches and derivatives thereof, e.g.mono- or di-esters with phosphoric acid, cellulose types and theirderivatives, xanthan gums, carrageenans. Heteropolysaccharides includexanthan gum such as Keltrol® from Kelco, and Natrosol® 250 HHR fromHerkules. The viscosity-increasing agent may be a starch compound. Theviscosity-increasing agent may be a hydroxypropyl starch phosphate. Anexample of a hydroxypropyl starch phosphate is Structure® XL from AkzoNobel. The thickening polymer may be a hydroxethyl cellulose. Thehydroxethyl cellulose may conform to the formula below:

A suitable hydroxethyl cellulose is Cellosize™ HEC QP 4400 from Dow.

The thickening polymer may be a cationic thickening polymer. Thethickening polymer may comprise a hydrocarbon backbone substituted withan amino-group containing sidechain. The thickening polymer may be acationic thickening polymer comprising a quaternary amine group,alternatively a quaternary ammonium group. The thickening polymer mayhave the below structure:

The thickening polymer may be a Polyquaternium-37. Polyquaternium-37 isa poly(2-methacryloxyethyltrimethylammonium chloride). Polyquaternium-37can be available from BASF via the product Salcare® SC 96 FROM BASF,which has the INCI name: Polyquaternium-37 (and) Propylene GlycolDicaprate Dicaprylate (and) PPG-1 Trideceth-6. Polyquaternium-37 is alsoavailable as: Syntran PC 5320 (Interpolymer Corporation); Ultragel® 300from Cognis GmbH; OriStar PQ37 from Orient Stars LLC; Synthalen CN from3V Group; Synthalen CR from 3V Group; Synthalen CU from 3V Group;Cosmedia® Triple C from Cognis GmbH, which has the INCI:Polyquaternium-37, Dicaprylyl Carbonate, Lauryl Glucoside.

Where the composition comprises a thickening polymer being a cationicthickening polymer comprising a quaternary amine group, alternatively aquaternary ammonium group, the composition may have a pH in the range 3to 5, or from 3.5 to 4.5. The pH range can be useful in ensuring thatthe thickening polymer does not act as a nucleophile.

Pigments

The composition comprises one or more coloured materials or one or morepigments. The composition may comprise one or more pigments. The one ormore pigments may be one or more coloured pigments which impart coloureffects to the product mass or to the hair, or they may be lustre effectpigments which impart desirable and aesthetically pleasing lustreeffects to the composition or to the keratin fibres. The colour orlustre effects on the hair are preferably temporary, i.e. they lastuntil the next hair wash and can be removed again by washing the hairwith customary shampoos.

The composition may comprise one or more pigments having a D₅₀ particlediameter of from 5 micron to 60 micron. Particle diameter is representedby D₅₀, which is the median diameter by volume. D₅₀ is measured with aMalvern Mastersizer 2000, which is a laser diffraction particle sizerand it is measured according to ISO 13320:2009(en) with Hydro 2000G orHydro 2000S where the dispersant is water or ethanol. Detection range isfrom 0.02 micron to 2000 micron. D₅₀ is expressed as x₅₀ in ISO13320:2009(en). Laser diffraction measures particle size distributionsby measuring the angular variation in intensity of light scattered as alaser beam passes through a dispersed particulate sample analyser andthe particle size is reported as a volume equivalent sphere diameter. Adiscussion of calculating D₅₀ is provided in Barber et al,Pharmaceutical Development and Technology, 3(2), 153-161 (1998), whichis incorporated herein by reference.

The composition may comprise one or more pigments having a D₅₀ particlediameter of from 10 micron to 40 micron. The one or more pigments may bepresent in the composition in an undissolved form. The composition maycomprise from 0.01% to 25%, or from 0.1% to 20% pigment, or from 1% to15%, or from 4% to 10% of the one or more pigments.

The one or more pigments may be colorants which are virtually insolublein the composition, and may be inorganic or organic. Inorganic-organicmixed pigments are also possible. The composition may comprise one ormore inorganic pigments. The advantage of one or more inorganic pigmentscan be their excellent resistance to light, weather and temperature. Theone or more inorganic pigments may be of natural origin, and are, forexample, derived from material selected from the group consisting ofchalk, ochre, umber, green earth, burnt sienna, and graphite.

The one or more pigments may be one or more white pigments, such as, forexample, titanium dioxide or zinc oxide, or may be one or more blackpigments, such as, for example, iron oxide black, or may be one or morecoloured pigments, such as, for example, ultramarine or iron oxide red,lustre pigments, metal effect pigments, pearlescent pigments, andfluorescent or phosphorescent pigments. The one or more pigments may beone or more coloured, non-white pigments. The one or more pigments maybe selected from the group consisting of metal oxides, hydroxides andoxide hydrates, mixed phase pigments, sulfur-containing silicates, metalsulfides, complex metal cyanides, metal sulfates, chromates andmolybdates, and the metals themselves (bronze pigments). The one or morepigments may be selected from the group consisting of are titaniumdioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI77492), red and brown iron oxide (CI 77491), manganese violet (CI77742), ultramarine (sodium aluminium sulfosilicates, CI 77007, PigmentBlue 29), chromium oxide hydrate (CI 77289), Prussian blue (ferricferrocyanide, CI 77510), carmine (cochineal), and combinations thereof.

The one or more pigments may be pearlescent and coloured pigments basedon mica which are coated with a metal oxide or a metal oxychloride, suchas titanium dioxide or bismuth oxychloride, and optionally furthercolour-imparting substances, such as iron oxides, Prussian blue,ultramarine, and carmine. The colour exhibited by the pigment can beadjusted by varying the layer thickness. Such pigments are sold, forexample, under the trade names Rona®, Colorona®, Dichrona®, RonaFlair®,Ronastar®, Xirona® and Timiron® all of which are available from Merck,Darmstadt, Germany. For example, Xirona® is a brand for colour travelpigments that display colour shifting effects depending on the viewingangle and are based on either natural mica, silica (SiO₂) or calciumaluminium borosilicate flakes, coated with varying layers of (titaniumdioxide) (TiO₂).

Pigments from the line KTZ® from Kobo Products, Inc., 3474 So. ClintonAve., So. Plainfield, USA, are also useful herein, in particular theSurface Treated KTZ® Pearlescent Pigments from Kobo. Particularly usefulare KTZ® FINE WHITE (mica and TiO₂) having a D₅₀ particle diameter of 5to 25 micron and also KTZ® CELESTIAL LUSTER (mica and TiO₂, 10 to 60micron) as well as KTZ® CLASSIC WHITE (mica and TiO₂, 10 to 60 micron).Also useful are SynCrystal Sapphire from Eckart Effect Pigments, whichis a blue powder comprising platelets of synthetic fluorphlogopitecoated with titanium dioxide, ferric ferrocyanide and small amounts oftin oxide. Also useful is SYNCRYSTAL Almond also from Eckart, which is abeige powder with a copper reflection colour and is composed ofplatelets of synthetic fluorphlogopite and coated with titanium dioxideand iron oxides. Also useful is Duocrome® RV 524C from BASF, whichprovides a two colour look via a lustrous red powder with a violetreflection powder due to its composition of mica, titanium dioxide andcarmine.

The one or more pigments may be one or more organic pigments. The one ormore organic pigment may be selected from the group consisting ofnatural pigments sepia, gamboge, bone charcoal, Cassel brown, indigo,chlorophyll and other plant pigments.

The one or more organic pigment may be one or more synthetic organicpigments which may be selected from the group consisting of azopigments, anthraquinoids, indigoids, dioxazine, quinacridone,phthalocyanine, isoindolinone, perylene and perinone, metal complex,alkali blue, diketopyrrolopyrrole pigments, and combinations thereof.

The one or more pigments may be selected from the group consisting ofiron oxide, titanium dioxide, mica, borosilicate, and combinationsthereof. The one or more pigments may comprise an iron oxide (Fe₂O₃)pigment. The one or more pigments may comprise a combination of mica andtitanium dioxide.

Coloured Material

The composition comprises one or more coloured materials. The one ormore coloured materials may be particulate in form. The one or morecoloured materials may be selected from the group consisting of colouredfibres, coloured beads, coloured particles such as nano-particles,coloured polymers comprising covalently attached dyes, liquid crystals,particles having diffraction properties, UV absorber and photoprotectivesubstances, pressure- or light-sensitive pigments, and combinationsthereof.

The one or more coloured materials may be capable of changing colour viaa mechanism selected from the group consisting of thermochromism,photochromism, hydrochromism, magnetochromism, electrochromism,piezochromism, chemichromism, mechano-optics. Suitable materials include3D Magnetic Pigments, Glow Dust, Fluorescent Pigments, Thermo Dust,Chameleon Pigments and other colour changing materials from Solar ColorDust (http://solarcolordust.com/).

The composition may comprise a photoprotective substance. Thecomposition may comprise from 0.01 to 10%, or from 0.1 to 5%, or from0.2 to 2% of the photoprotective substance. Useful photoprotectivesubstances are specified in EP1084696A1 from § 0036 to § 0053, which isincorporated herein by reference. The photoprotective substance may beselected from the group consisting of 2-ethylhexyl 4-methoxy-cinnamate,methyl methoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonicacid, polyethoxylated p-aminobenzoates, di-butylhydroxytoluene (BHT),and mixtures thereof.

The composition may comprise from 0.01% to 10%, or from 0.05% to 5% ofthe particulate substance. The particulate substances may be substanceswhich are solid at room temperature (23° C.) and are in the form ofparticles. The particulate substance may be selected from the groupconsisting of silica, silicates, aluminates, clay earths, mica, andinsoluble salts. The particulate substance may be selected from thegroup consisting of insoluble inorganic metal salts, metal oxides,minerals and insoluble polymer particles. The particulate substance maybe titanium dioxide.

The particulate substance may be present in the composition in anundissolved, or stably dispersed form, and, following application to thehair and evaporation of the solvent, can deposit on the hair in solidform.

The particulate substance may be selected from the group consisting ofsilica (silica gel, silicon dioxide) and metal salts, in particularinorganic metal salts. The particulate substance may be silica. Theparticulate substance may be selected from the group consisting of metalsalts such as alkali metal or alkaline earth metal halides, e.g. sodiumchloride or potassium chloride; alkali metal or alkaline earth metalsulfates, such as sodium sulfate or magnesium sulfate.

Solvent

The composition comprises water. The water acts as a solvent. Water isuseful because it provides a hydrophilic phase, which the hydrophilicportions of the components can interact with. Water is also usefulbecause it provides a fluid phase meaning that the composition can be inliquid form and therefore easily mixed with other fluids. Thecomposition may comprise from 40% to 90%, or 50% to 85%, or from 55% to80% of water. The solvent may comprise water and wherein the compositionmay comprise from 50% to 85% of water.

The composition may be an aqueous, alcoholic or aqueous-alcoholiccomposition comprising at least 10% of water. The composition maycomprise further water-miscible or water-soluble solvents. Thecomposition may comprise at least one C1-C5 alkyl monohydric alcohol, orat least one C2-C3 alkyl alcohols. The composition may comprise ethanoland/or isopropanol. The composition may comprise a co-solvent. Theco-solvent may be a cosmetically acceptable organic solvent or a mixtureof solvents with a boiling point below 400° C. The composition maycomprise from 0.1% to 15% of a co-solvent, or from 1% to 10% of aco-solvent. The co-solvent may be selected from the group consisting ofunbranched or branched hydro-carbons, such as pentane, hexane,isopentane; cyclic hydrocarbons, such as cyclopentane and cyclohexane.The composition may comprise glycerol, ethylene glycol, propyleneglycol, or a mixture thereof.

Anti-Freeze Agent

The composition may comprise an anti-freeze agent. An anti-freeze agenthas the advantage that it lowers the freezing point of a composition andconsequently prevent the composition from freezing, which can preventany unwanted side effects of freezing and/or subsequent thawing. Theanti-freeze agent may be a volatile alcohol, for example a volatilealcohol having from 1 to 8 carbon atoms and being miscible in water.

The composition may comprise from 0.5% to 30% of the volatile alcohol,wherein the volatile alcohol may have from 1 to 8 carbon atoms and maybe miscible in water. Miscibility in water is useful in view of theadvantages of using water as a solvent. Indeed, the solvent may be waterand/or the majority of the solvent is water. Since the present firstaspect is “for providing a film on keratin fibres”, the volatility ofthe alcohol can be chosen such that solvent and other non-film-formingcompounds evaporate.

Preservative

The composition comprises 2-phenoxyethanol and/or phenylmethanol.2-phenoxyethanol and phenylmethanol are preservatives. The compositionmay comprise 2-phenoxyethanol as sole preservative. The composition maycomprise phenylmethanol as sole preservative. The composition maycomprise from 0.01% to 5% of the preservative, or from 0.1% to 2%, orfrom 0.5% to 1.5% of the preservative. The preservative may be a mixtureof benzyl alcohol and phenoxyethanol. The composition is substantiallyfree of esters of parahydroxybenzoic acid. Esters of parahydroxybenzoicacid are commonly known as parabens. Parabens are not preferred by someconsumers. The composition is substantially free of isothiazolinonecompounds. The composition may be substantially free of benzoatecompounds. Benzoate compounds are not preferred in view of the potentialfor instability and/or precipitation of the composition. The compositionmay be substantially free of1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione.

Perfume

The composition may comprise one or more perfumes. The composition maycomprise from 0.001% to 2% of the one or more perfumes. The one or morepigments and/or the one or more coloured materials may have perfumedcoating. The one or more perfumes may also be provided via anencapsulated perfume i.e. a perfume provided inside a microcapsule.

The microcapsule may feature friction-triggered release technology i.e.the contents of the microcapsule is released upon exposing themicrocapsule friction. Said friction could be the action of sponging thecomposition according to the present invention onto the hair or combingthe hair after the composition has been applied. The microcapsule may bea friable microcapsule. A friable microcapsule is configured to releasethe core material when the outer shell is ruptured. The microcapsule maycomprise a shell made from a synthetic polymeric material. Themicrocapsule may comprise a core material and a shell surrounding thecore material, wherein the shell comprises: a plurality of aminemonomers selected from the group consisting of aminoalkyl acrylates,alkyl aminoalkyl acrylates, dialkyl aminoalkyl acrylates, aminoalkylmethacrylates, alkylamino aminoalkyl methacrylates, dialkyl aminoalkylmethacrylates, tertiarybutyl aminethyl methacrylates, diethylaminoethylmethacrylates, dimethylaminoethyl methacrylates, dipropylaminoethylmethacrylates, and mixtures thereof; and a plurality of multifunctionalmonomers or multifunctional oligomers. The shell may consist of apolyacrylate material, such as a polyacrylate random copolymer.

the microcapsule may feature moisture-triggered release technology i.e.the contents of the microcapsule is released upon contact with moisture.The microcapsule may comprise cyclic oligosaccharides, or themicrocapsule matrix or shell is made from cyclic oligosaccharides.“Cyclic oligosaccharide” means a cyclic structure comprising six or moresaccharide units. The cyclic oligosaccharides may have six, seven, oreight saccharide units or combinations thereof. It is common in the artto refer to six, seven and eight membered cyclic oligosaccharides as α,β, and γ, respectively. The cyclic oligosaccharides may be selected fromthe cyclodextrins: methyl-α-cyclodextrins, methyl-β-cyclodextrins,hydroxypropyl-α-cyclodextrins, hydroxypropyl-β-cyclodextrins, andmixtures thereof. The cyclodextrins may be in the form of particles. Thecyclodextrins may also be spray-dried.

The one or more perfumes may be an animal fragrance or a plantfragrance. The animal fragrance may be selected from consisting of muskoil, civet, castoreum, ambergris, and mixtures thereof. The plantfragrance may be selected from consisting of nutmeg extract, cardomonextract, ginger extract, cinnamon extract, patchouli oil, geranium oil,orange oil, mandarin oil, orange flower extract, cedarwood, vetyver,lavandin, ylang extract, tuberose extract, sandalwood oil, bergamot oil,rosemary oil, spearmint oil, peppermint oil, lemon oil, lavender oil,citronella oil, chamomille oil, clove oil, sage oil, neroli oil,labdanum oil, eucalyptus oil, verbena oil, mimosa extract, narcissusextract, carrot seed extract, jasmine extract, olibanum extract, roseextract, and mixtures thereof.

The one or more perfumes may be selected from the group consisting ofacetophenone, adoxal, aldehyde C-12, aldehyde C-14, aldehyde C-18, allylcaprylate, ambroxan, amyl acetate, dimethylindane derivatives,α-amylcinnamic aldehyde, anethole, anisaldehyde, benzaldehyde, benzylacetate, benzyl alcohol and ester derivatives, benzyl propionate, benzylsalicylate, borneol, butyl acetate, camphor, carbitol, cinnamaldehyde,cinnamyl acetate, cinnamyl alcohol, cis-3-hexanol and ester derivatives,cis-3-hexenyl methyl carbonate, citral, citronnellol and esterderivatives, cumin aldehyde, cyclamen aldehyde, cyclo galbanate,damascones, decalactone, decanol, estragole, dihydromyrcenol, dimethylbenzyl carbinol, 6,8-dimethyl-2-nonanol, dimethyl benzyl carbinylbutyrate, ethyl acetate, ethyl isobutyrate, ethyl butyrate, ethylpropionate, ethyl caprylate, ethyl cinnamate, ethyl hexanoate, ethylvalerate, ethyl vanillin, eugenol, exaltolide, fenchone, fruity esterssuch as ethyl 2-methyl butyrate, galaxolide, geraniol and esterderivatives, helional, 2-heptonone, hexenol, α-hexylcinnamic aldehyde,hydroxycitrolnellal, indole, isoamyl acetate, isoeugenol acetate,ionones, isoeugenol, isoamyl iso-valerate, iso E super, limonene,linalool, lilial, linalyl acetate, lyral, maj antol, mayol, melonal,menthol, p-methylacetophenone, methyl anthranilate, methyl cedrylone,methyl dihydrojasmonate, methyl eugenol, methyl ionone,methyl-α-naphthyl ketone, methylphenylcarbinyl acetate, mugetanol,γ-nonalactone, octanal, phenyl ethyl acetate, phenyl-acetaldehydedimethyl acetate, phenoxyethyl isobutyrate, phenyl ethyl alcohol,pinenes, sandalore, santalol, stemone, thymol, terpenes, triplal,triethyl citrate, 3,3,5-trimethylcyclohexanol, γ-undecalactone,undecenal, vanillin, veloutone, verdox, and mixtures thereof.

pH

The pH of the composition may be from 3.0 to 11.0, or from 3.5 to 8.0,or from 3.5 to 5.5, or from 4.0 to 5.0. The pH is useful in ensuringcosmetic compatibility and stability of the composition. For example, atoo high or too low pH can cause components to precipitate, which couldlead to undesirable residues on hair.

The composition may comprise a pH modifier and/or buffering agent. Theamount is sufficiently effective to adjust the pH of thecomposition/formulation. Suitable pH modifiers and/or buffering agentsfor use herein include, but are not limited to ammonia, alkanolaminessuch as monoethanolamine, diethanolamine, triethanolamine,monopropanolamine, dipropanolamine, tripropanolamine, tripropanolamine,2-amino-2-methyl-1-propanol, and 2-amino-2-hydroxymethyl-1,3,-propandioland guanidium salts, alkali metal and ammonium hydroxides andcarbonates, preferably sodium hydroxide, sodium silicate, sodium metasilicate and ammonium carbonate, and acidulents such as inorganic andinorganic acids, e.g., phosphoric acid, acetic acid, ascorbic acid,citric acid or tartaric acid, hydrochloric acid, and mixtures thereof.

Rheology

The composition may have a viscosity of from 30 mPa·s to 1000 mPa·s. Theviscosity is measured at 23° C. using a HAAKE Rotation Viscometer VT 550with cooling/heating vessel and sensor systems according to DIN 53019 ata shear rate of 12.9 s⁻¹. The composition may have a viscosity of from100 mPa·s to 500 mPa·s, or from 150 mPa·s to 450 mPa·s, or from 200mPa·s to 400 mPa·s, or from 250 mPa·s to 350 mPa·s. The composition mayhave a viscosity of from 100 mPa·s to 200 mPa·s. The viscosity range isuseful in view of helping to prevent the composition from dripping ontoclothes and/or surrounding material. Furthermore, when the viscosity istoo high, the composition cannot easily be mixed.

The composition may have a tangent delta of less than 2 at an angularfrequency of 1 Hz at 23° C. and at 1% strain. Tangent delta (also knownas: tan delta, tan [6], loss tangent, loss factor) is the ratio ofviscous modulus (G″) to elastic modulus (G) and is a quantifier of thepresence and extent of elasticity in a fluid. How to calculate the tandelta is shown below:

G^(′) = Storage  Modulus G^(″) = Loss  Modulus tan  δ = Loss  Factor$\frac{G^{''}}{G^{\prime}} = {\tan\;\delta}$${{G^{*}}(w)} = {{{G^{\prime}(w)} + {{\mathbb{i}}\;{G^{''}(w)}}} = \sqrt{G^{\prime 2} + G^{''2}}}$Further information on equipment and methodology for calculating tangentdelta can be found in the Experimental section below. The compositionmay have a tangent delta of from 0.6 to 2 at an angular frequency of 1Hz at 23° C. and at 1% strain. The composition may have a tangent deltaof from 0.6 to 1.5, or from 0.6 to 1.0 at an angular frequency of 1 Hzat 23° C. and at 1% strain.Hair Colouring Agent

The composition may further comprise a hair colouring agent. The haircolouring agent may be a direct dye. The composition may comprise atotal amount of from 0.001% to 4%, or from 0.005% to 3%, or from 0.01%to 2% of the direct dye. The presence of a direct dye and the proportionthereof is useful in that it can provide or enhance colouring/dyeing,particularly with regard to intensity.

The direct dye may be selected from the group consisting of nitro dyesto provide a blue colour, nitro dyes to provide a red colour, nitro dyesto provide a yellow colour, quinone dyes, basic dyes, neutral azo dyes,acid dyes, and mixtures thereof. The direct dye may be a nitro dye toprovide a blue colour. The direct dye may be a nitro dye to provide ared colour. The direct dye may be a nitro dye to provide a yellowcolour. The direct dye may be a quinone dye. The direct dye may be abasic dye. The direct dye may be a neutral azo dye. The direct dye maybe an acid dye.

The direct dye may be selected from the group consisting of Acid dyessuch as Acid Yellow 1, Acid Orange 3, Acid Black 1, Acid Black 52, AcidOrange 7, Acid Red 33, Acid Yellow 23, Acid Blue 9, Acid Violet 43, AcidBlue 16, Acid Blue 62, Acid Blue 25, Acid Red 4, Basic Dyes such asBasic Brown 17, Basic Red 118, Basic Orange 69, Basic Red 76, BasicBrown 16, Basic Yellow 57, Basic Violet 14, Basic Blue 7, Basic Blue 26,Basic Red 2, Basic Blue 99, Basic Yellow 29, Basic Red 51, Basic Orange31, Basic Yellow 87,4-(3-(4-amino-9,10-dioxo-9,10-dihydroanthracen-1-ylamino)propyl)-4-methylmorpholin-4-ium-methylsulfate,(E)-1-(2-(4-(4,5-dimethylthiazol-2-yl)diazenyl)phenyl)(ethyl)amino)ethyl)-3-methyl-1H-imidazol-3-iumchloride,(E)-4-(2-(4-(dimethylamino)phenyediazenyl)-1-methyl-1H-imidazol-3-ium-3-yl)butane-1-sulfonate,(E)-4-(4-(2-methyl-2-phenylhydrazono)methyl)pyridinium-1-yl)butane-1-sulfonate,N,N-dimethyl-3-(4-(methylamino)-9,10-dioxo-4a,9,9a,10-tetrahydroanthracen-1-ylamino)-N-propylpropan-1-aminiumbromide, Disperse Dyes such as Disperse Red 17, Disperse Violet 1,Disperse Red 15, Disperse Violet 1, Disperse Black 9, Disperse Blue 3,Disperse Blue 23, Disperse Blue 377, Nitro Dyes such as1-(2-(4-nitrophenylamino)ethyl)urea,2-(4-methyl-2-nitrophenylamino)ethanol, 4-nitrobenzene-1,2-diamine,2-nitrobenzene-1,4-diamine, Picramic acid, HC Red No. 13,2,2′-(2-nitro-1,4-phenylene)bis(azanediyl)diethanol, HC Yellow No. 5, HCRed No. 7, HC Blue No. 2, HC Yellow No. 4, HC Yellow No. 2, HC OrangeNo. 1, HC Red No. 1, 2-(4-amino-2-chloro-5-nitrophenylamino)ethanol, HCRed No. 3, 4-amino-3-nitrophenol, 4-(2-hydroxyethylamino)-3-nitrophenol,2-amino-3-nitrophenol, 2-(3-(methylamino)-4-nitrophenoxy)ethanol,3-(3-amino-4-nitrophenyl)propane-1,2-diol, HC Yellow No. 11, HC VioletNo. 1, HC Orange No. 2, HC Orange No. 3, HC Yellow No. 9, HC Red No. 10,HC Red No. 11, 2-(2-hydroxyethylamino)-4,6-dinitrophenol, HC Blue No.12, HC Yellow No. 6, HC Yellow No. 12, HC Blue No. 10, HC Yellow No. 7,HC Yellow No. 10, HC Blue No. 9, 2-chloro-6-(ethylamino)-4-nitrophenol,6-nitropyridine-2,5-diamine, HC Violet No. 2,2-amino-6-chloro-4-nitrophenol, 4-(3-hydroxypropylamino)-3-nitrophenol,HC Yellow No. 13, 6-nitro-1,2,3,4-tetrahydroquinoxaline, HC Red No. 14,HC Yellow No. 15, HC Yellow No. 14,N2-methyl-6-nitropyridine-2,5-diamine,N1-allyl-2-nitrobenzene-1,4-diamine, HC Red No. 8, HC Green No. 1, HCBlue No. 14, and Natural dyes such as Annato, Anthocyanin, Beetroot,Carotene, Capsanthin, Lycopene, Chlorophyll, Henna, Indigo, Cochineal.

Other Features of the Composition of the First Aspect

The composition may comprise one or more radical scavengers, which maybe present in a sufficient amount to reduce damage to the hair. The oneor more radical scavengers may be advantageously selected such that itis not an alkalising agent. The one or more radical scavengers may beselected from the group consisting of: alkanolamines, amino sugars,amino acids, and mixtures thereof. The one or more radical scavengersmay be selected from the group consisting of: monoethanolamine,3-amino-1-propanol, 4-amino-1-butanol, 5-amino-1-pentanol,1-amino-2-propanol, 1-amino-2-butanol, 1-amino-2-pentanol,1-amino-3-pentanol, 1-amino-4-pentanol, 3-amino-2-methylpropan-1-ol,1-amino-2-methylpropan-2-ol, 3-aminopropane-1,2-diol, glucosamine,N-acetylglucosamine, glycine, arginine, lysine, proline, glutamine,histidine, serine, tryptophan, and potassium, sodium and ammonium saltsof the above, and mixtures thereof. The one or more radical scavengersmay be selected from the group consisting of: benzylamine, glutamicacid, imidazole, di-tert-butylhydroxytoluene, hydroquinone, catechol,and mixtures thereof. The composition may be substantially free ofradical scavenger.

The composition may comprise one or more chelants. The composition maycomprise one or more chelants in an amount sufficient to reduce theamount of metals available to interact with composition components.Chelants are also known as chelators and chelating agents. The one ormore chelants may be selected from the group consisting of:diamine-N,N′-dipolyacid, monoamine monoamide-N,N′-dipolyacid, andN,N′-bis(2-hydroxybenzyl)ethylenediamine-N,N′-diacetic acid chelants(e.g. EDDS (ethylenediaminedisuccinic acid)), carboxylic acids (e.g.aminocarboxylic acids), phosphonic acids (e g aminophosphonic acids),polyphosphoric acids (in particular straight polyphosphoric acids),salts and derivatives thereof, and mixtures thereof. The one or morechelants may be ethylenediamine tetraacetic acid (EDTA) and/or editronicacid. The one or more chelants may be histidine.

The composition may be substantially free of persulfate. The method maynot encompass or include bleaching the hair.

Exemplary Embodiments of the First Aspect

A composition for providing a film on keratin fibres, is provided andcomprises:

(a) a film-forming aminosilicone polymer, wherein the film-formingaminosilicone polymer comprises amino side chains, and wherein thefilm-forming aminosilicone polymer as a weight average molecular weightof from 10,000 Dalton to 60,000 Dalton;

(b) a silicone resin;

(c) an ether of a water-soluble polyhydric alcohol;

(d) a thickening system comprising:

-   -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton;    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer;        (e) one or more coloured materials or one or more pigments;        (f) water;        (g) 2-phenoxyethanol and/or phenylmethanol;        wherein the composition is substantially free of esters of        parahydroxybenzoic acid; and wherein the composition is        substantially free of isothiazolinone compounds.        The composition may further comprise a particulate substance        being silica.

A composition for providing a film on keratin fibres, may be providedand may comprise:

(a) a film-forming aminosilicone polymer, wherein the film-formingaminosilicone polymer comprises amino side chains, and wherein thefilm-forming aminosilicone polymer as a weight average molecular weightof from 10,000 Dalton to 60,000 Dalton;

(b) a silicone resin;

(c) an ether of a water-soluble polyhydric alcohol;

(d) a thickening system comprising:

-   -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton;    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer;        (e) one or more coloured materials or one or more pigments;        (f) water;        (g) 2-phenoxyethanol and/or phenylmethanol;        and wherein the composition is substantially free of esters of        parahydroxybenzoic acid;        and wherein the composition is substantially free of        isothiazolinone compounds        and wherein the composition comprises one or more pigments        having an average D₅₀ particle diameter of from 5 micron to 60        micron.

A composition for providing a film on keratin fibres, may be providedand comprised:

(a) from 0.1% to 3% of a film-forming aminosilicone polymer, wherein thefilm-forming aminosilicone polymer comprises amino side chains, andwherein the film-forming aminosilicone polymer as a weight averagemolecular weight of from 10,000 Dalton to 60,000 Dalton;(b) a silicone resin;(c) an ether of a water-soluble polyhydric alcohol;(d) from 0.5% to 10% of a thickening system comprising:

-   -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton;    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer;        (e) from 1% to 10% of one or more coloured materials or one or        more pigments;        (f) water;        (g) 2-phenoxyethanol and/or phenylmethanol;        wherein the composition is substantially free of esters of        parahydroxybenzoic acid;        wherein the composition is substantially free of isothiazolinone        compounds;        wherein the composition comprises pigment having an average D₅₀        particle diameter of from 5 micron to 60 micron; and        wherein the one or more pigments are selected from the group        consisting of iron oxide, titanium dioxide, mica, borosilicate,        and combinations thereof.        2^(nd) Aspect

A method for providing a film comprising one or more pigments or one ormore coloured materials onto keratin fibres, is provided and comprisedapplying the composition as set out herein above onto keratin fibres andallowing the keratin fibres to dry or drying them. The method maycomprise applying the composition as set out herein above onto keratinfibres and then drying them with a device selected from the groupconsisting of blow dryer, heated irons, heated hood, and combinationsthereof.

The drying may be carried out using a hair dryer or a drying hood. Thedrying may be carried out at a temperature of 28° C. to 40° C. Thetemperature is useful in that it assists in the evaporation of solventand other volatile compounds and thus allows excellent film formation.The method may comprise drying the keratin fibres with a device selectedfrom the group consisting of blow dryer, heated irons, heated hood, andcombinations thereof.

The method may comprise applying a composition as set out herein aboveonto keratin fibres and allowing the keratin fibres to dry or dryingthem; and subsequently, applying a formulation comprising a siliconeresin onto keratin fibres and allowing the keratin fibres to dry ordrying them. The composition may comprise a white pigment or a blackpigment.

The method may comprise applying a first composition as set out hereinabove onto keratin fibres and allowing the keratin fibres to dry ordrying them; and subsequently, applying a second composition as set outherein above onto keratin fibres and allowing the keratin fibres to dryor drying them; wherein the first composition may comprise a firstpigment exhibiting a first colour and the second composition maycomprise a second pigment exhibiting a second colour. the first colourmay be white or black. The second colour may be neither white nor black.The first pigment may comprise titanium dioxide or carbon.

3^(rd) Aspect

A kit is provided and comprised: the composition as set out hereinabove; optionally a formulation comprising one or more pigments and/orone or more coloured materials; an applicator. the kit consists of apackaging comprising the composition as set out herein above and asponge head; and wherein the composition may comprise one or morepigments and/or one or more coloured materials. The kit may comprise amulti-compartment package comprising a first compartment and a secondcompartment; wherein the first compartment may comprise the compositionas set out herein above and the second compartment may comprise the oneor more pigments and/or the one or more coloured materials.

The kit may comprise a first composition as set out herein abovecomprising a first pigment and a second composition as set out hereinabove comprising a second pigment; wherein the first pigment and thesecond pigment exhibit different colours.

4^(th) Aspect

A fourth aspect relates to the use of the kit according to the 3^(rd)aspect for applying pigment and/or coloured material to keratin fibres.

EXAMPLES

The following examples further describe and demonstrate embodimentswithin the scope of the present invention. The examples are given solelyfor the purpose of illustration, and are not to be construed aslimitations of the present invention since many variations thereof arepossible without departing from its scope.

Composition Examples

Example Ingredient 1 2 3 4 5 6 7 8 9 10 11 12 BELSIL ADM 10   8   12  15   14   18   15   14   12   15   15   15   8301 E¹ Salcare ® SC 96²0.6  0.75  0.75  0.75 —  0.75  0.75 —  0.75 0.6 0.5  0.75 2-hydroxyethyl— — — — 0.2 — — — — — — — cellulose³ Xanthan gum⁴ — — — — — — — 0.3 — —— — PEG-45M⁵ 0.2 0.3 — — 0.1 0.2 0.2 — — 0.2 0.2 0.2 PEG-23M⁶ — — 0.2 —— — — — 0.2 — — — PEG-90M⁷ — — — 0.1 — — — — — — — — PEG-7M⁸ — — — — 0.3— — — — — — — PEG-180M⁹ — — — — — — — 0.1 — — — — Tergitol^($) — 0.5 —0.5 — — 0.5 — 0.5 0.5 0.5 0.5 Pigment^(§) 5.0 5.0 5.0 — 5.0 5.0 5.0 5.05.0 5.0 5.0 5.0 Aquasolved^(#) — — — 2.5 2.5 — — 2.3 — — — — Ethanol 1.01.5 2.0 — — 1.0 1.5 2.0 — 1.0 1.0 1.0 Preservative* 1.0 2.0 1.5 0.5 1.01.5 0.5 1.0 1.0 1.0 1.0 1.0 Perfume — 0.1 0.07 0.1 — — — 0.2 0.2 0.1 0.10.1 Deionised water QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP KEY:¹= from Wacker, aqueous mixture ofpoly[3-((2-aminoethyl)amino)propyl]methyl(dimethyl)siloxane(hydroxyterminated), octamethylcyclotetrasiloxane, MQ resin, ethyleneglycol monohexyl ether and diethyleneglycol monobutylether; ²= Salcare ®SC 96 from BASF, which has the INCI name: Polyquaternium-37 (and)Propylene Glycol Dicaprate Dicaprylate (and) PPG-1 Trideceth-6; ³=Cellosize ™ HEC QP 4400 from Dow; ⁴= Keltrol ® from Kelco or Natrosol ®250 HHR from Herkules; ⁵= POLYOX WSR N-60K from Dow has formulaH(OCH₂CH₂)_(n)OH wherein n is an integer and where n has an averagevalue of 45,000 and the weight average molecular weight is 2,000,000Dalton; ⁶= POLYOX WSR N-12K from Dow has the formula H(OCH₂CH₂)_(n)OHwherein n is an integer with an average value of 23,000 and the weightaverage molecular weight is 1,000,000 Dalton; ⁷= POLYOX WSR-301 from Dowhas the formula H(OCH₂CH₂)_(n)OH wherein n is an integer with an averagevalue of 90,000 and the weight average molecular weight is 4,000,000Dalton; ⁸= POLYOX N-750 from Dow has the formula H(OCH₂CH₂)_(n)OHwherein n is an integer with an average value of 7,000 and the weightaverage molecular weight is 300,000 Dalton; ⁹= POLYOX WSR-308 from Dow,as formula H(OCH₂CH₂)_(n)OH wherein n is an integer and where n has anaverage value of 180,000 and has a weight average molecular weight of8,000,000 Dalton; ^($)= C11-15 Pareth-9 and is the polyethylene glycolether of a mixture of synthetic C11-15 fatty alcohols with an average of9 moles of ethylene oxide. *= 2-phenoxyethanol and/or phenylmethanol;^(#)= from Firmenich; ^(§)= pigment selected from: mica and/or ironoxides; Colorona Bronze Fine; SynCrystal Almond; Xirona Le Rouge;DUOCROME RV 524C; SynCrystal Jade; Colorona Precious Gold; Ronastar Red;Syncrystal Sapphire; Impact Silver Rutile; KTZ Misterioso Pewter; andcombinations thereof.

Experimental Dripping Test

Various compositions are tested in order to elucidate advantageousdripping behaviour of various thickening systems. A base composition isprepared that comprises water, an aminosilicone polymer(polydimethylsiloxane polymer having graft amino groups), silicone resin(MQ resin), and mixture of diethyleneglycol monobutylether and ethyleneglycol monohexyl ether. As per the below table, a deposition enhancer ora thickening polymer is added to the base composition in the amounts (wt%) indicated. 0.5 g of pigment is then added to 9.5 g of thiscomposition. The composition is applied to hair and the drippingbehaviour observed and, where relevant, the number of drips in 30seconds counted.

Deposition Thickening Visual observations enhancer polymer onconsistency Dripping test 1 — — Watery 15 drips in 30 s 2 — 1* Creamy Nodripping 3 — 0.5^(#) Creamy No dripping 4 1^(§) — Gel-like, sticky Nodripping 5 — 0.8^(#) Creamy No dripping 6 0.2^(β) — Watery, stringy 2drips in 30 s 7 0.2^(§) — Watery 2 drips in 30 s Key: *= Cellosize(Hydroxethylcellulose); ^(#)= Salcare SC 96 from BASF; ^(β)= POLYOX WSR308 (Dow), which has a M. Wt. of 8 million Dalton; ^(§)= Polyox WSR N60K(Dow), which has a M. Wt. of 2 million Dalton.Conclusions: Compositions 2 and 3 performed the best. When comparingcompositions 6 and 7, it is apparent that the higher weight averagemolecular weight of the deposition enhancer caused compositionstringiness. Composition 4 demonstrates that deposition enhancer alonedoes not provide the preferred creamy consistency. Only the compositionscomprising a thickening polymer exhibited the preferred creamyconsistency.Rheology

The following compositions are prepared.

Thickening Deposition Water Pigment^(§) Z EtOH polymer* enhancer^(#)Phenoxy-ethanol Total A 85 0 15 0 0 0 0 100 B 77.3 5 15 1 0.75 0 1 100 C77.8 5 15 1 0 0.2 1 100 D 77.6 5 15 1 0.25 0.2 1 100 E 77.3 5 15 1 0.50.2 1 100 F 77.1 5 15 1 0.75 0.2 1 100 G 76.8 5 15 1 1 0.2 1 100 KEY: Z= Wacker ® HC303 (as per BELSIL ADM 8301 E above commerciallyavailable); EtOH = ethanol; *= Salcare ® SC96 from BASF; ^(#)= PEG-45M(Polyox WSR N-60K) from Dow; ^(§)= copper pigment.The viscosity of these compositions is measured and an averagecalculated. A simple flow viscosity experiment provides information onhow fast the same quantity of composition flows down the same gradientand all other conditions equal. The dripping test is as per above.

Viscosity* Flow viscosity 1 2 3 Average (cm/s) Dripping test A 1.9 2.852.85 2.53 3.1 1 B 100 99.9 100 99.96 2.1 0 C 9.51 8.56 8.56 8.87 7.6 0 D45.6 44.7 43.7 44.66 3.6 0 E 124 123 122 123 2.2 0 F 319 318 317 318 1.50 G 757 755 756 756 1 0 KEY: *viscosity in mPa · s using a Haakeviscometer (64.50 1/s) MV DIN with 5 minute conditioning time.Consequently, compositions B and D to G fall within the viscosity scopeclaimed i.e. viscosity of from 30 mPa·s to 1000 mPa·s. Composition D hasthe lowest viscosity out of compositions B and D to G. Composition D hasthe fastest flow viscosity out of compositions B and D to G. CompositionG has the highest viscosity and also the slowest flow viscosity.

The time-dependent viscoelastic properties in the linear viscoelasticregion with an amplitude sweep are measured and compared. The storagemodulus and tangent delta are measured using a TA-Instruments AR2000exrheometer. In this experiment, different compositions are compared. Thecomponents of the composition are mixed together, and then homogenisedusing an IKA KS 501 digital at 160 rpm and then loaded it onto therheometer. The rheometer is used with the followingspecifications/conditions: upper geometry, 60 mm steel; lower geometry,Peltier Element; temperature, 23° C.; Pre-shear, 5 l/s, 1 min;equilibration, 2 min; normal force, off; gap: 650 μm. An amplitude sweep(strain sweep) was carried out with a strain of between 0.05% and 50%,with log data sampling (10 points/decade) and at a frequency of 1 Hz(6.283 rad/s).

These data are depicted in FIG. 1, which is also summarised in the belowtable.

Compo- Symbol in Thickening Deposition Tangent delta (at 1 sition FIGUREpolymer* enhancer^(#) Hz and 1% strain) B Δ triangle 0.75 0 is less than2 but greater than 0.6 D x cross 0.25 0.2 is greater than 2 E ⋄ diamond0.5 0.2 is greater than 2 F + plus 0.75 0.2 is less than 2 but greaterthan 0.6 G ◯ circle 1 0.2 is less than 2 but greater than 0.6 KEY: *=Salcare ® SC96 from BASF; ^(#)= PEG-45M (Polyox WSR N-60K) from Dow.

Consequently, compositions D and E do not have a tangent delta of lessthan 2 at an angular frequency of 1 Hz at 23° C.

Color and Hair Performance: Influence of the MO Resin

The following compositions were prepared (all amounts are in wt %). Acomposition H comprises a MQ resin while a comparative composition Idoes not comprise a MQ resin. The comparative composition I is notwithin the scope of the present invention.

Anti- Thickening Deposition Phenoxy- freeze Water Pigment^(§) Z W EtOHpolymer* enhancer^(#) ethanol agent^($) Total H Qsp 5 15 0 2 0.75 0.2 10.5 100 I Qsp 5 0 15 2 0.75 0.2 1 0.5 100 KEY: Z = Wacker ® HC303(commercially available); W = Wacker ® HC303 as set out herein abovewithout any MQ resin; EtOH = ethanol; *= Salcare ® SC96 from BASF; ^(#)=PEG-45M (Polyox WSR N-60K) from Dow; ^(§)= copper pigment fromColorona ®; and ^($)= C₁₁₋₁₅ Pareth-9 and is the polyethylene glycolether of a mixture of synthetic C11-15 fatty alcohols with an average of9 moles of ethylene oxide.Hair StrandsCaucasian Hair color 4/0 Euro-Natural-HairHair strands having a width of 1.5 cm and a length of 10 cm.Available from Kerling International HaarfabrikApplication of Each of the Compositions H or I on Hair Strands

1.0 g of a composition H or a comparative composition I was applied on1.0 g of hair strands. The respective composition H or I was distributedinto the hair strands with the help of a brush or a sponge head. Thehair strands were flipped. The respective composition H or I was furtherdistributed until all hair fibers of the hair strands were completelyand evenly colored. Each treated hair strand was blow dried manuallywith a conventional blow dryer for 2 minutes. After each 30 seconds, thetreated hair strands were combed from the top to the bottom of the hairstrands.

Visual Assessment of the Color Effect/Intensity:

The hair strands treated with the composition H were compared to thehair strands treated with the comparative composition I under a D65light box. The assessment was rated as follows:

−3 −2 −1 0 1 2 3 Obvious Noticeable Slightly Equal Slightly NoticeableObvious worst worst worst better better better

The reference was a non-treated hair strand.

Hair strands treated with the composition H exhibited a noticeablebetter effect on hair than the reference.

Hair strands treated with the comparative composition I exhibited aslight worst effect on hair than the reference.

When the composition comprises a MQ resin, the color effect on hair isbetter noticeable than when the composition does not comprise a MQresin.

Effect of Hair Wash

The hairs strand treated with the respective composition H or I werewashed for 30 seconds with water then 30 seconds with 0.5 mL of WellaProfessionals Brilliance Shampoo, and then 30 seconds with water.

Each treated hair strand was blow dried manually with a conventionalblow dryer for 2 minutes. After each 30 seconds, the treated hairstrands were combed from the top to the bottom of the hair strands.

The hair strands treated with the composition H showed a good pigmentadhesion to the hair, by visual assessment.

However, the hair strands treated with the comparative composition Ionly showed a slight pigment adhesion to the hair, by visual assessment.

Hair Feel

The hair strands treated with the respective composition H or I werepulled through thumb and index fingers. The treated hair strands wereassessed versus an untreated hair strand. The hair strands treated withthe composition H showed a noticeable coated effect. However, the hairstrands treated with the comparative composition I only showed a slightcoated effect.

Water Dipping Test

The hair strands treated with the respective composition H or I weredipped for 15 times for 15 seconds in 200 mL of distillate water. Apicture was taken after the pigments have sedimented. It has beenobserved that the hair strands treated with the composition H lost fewpigments. However, the hair strands treated with the comparativecomposition I lost much more pigments versus the hair strands treatedwith the composition H.

CONCLUSION

When the hair strands are treated with the composition H which comprisesa MQ resin, versus the comparative composition I, the treated hairstrands exhibited an improved colored performance, with an increasedpigment adhesion on hair, and a better resistance to wash fastness.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm”

Every document cited herein, including any cross referenced or relatedpatent or application, is hereby incorporated herein by reference in itsentirety unless expressly excluded or otherwise limited. The citation ofany document is not an admission that it is prior art with respect toany invention disclosed or claimed herein or that it alone, or in anycombination with any other reference or references, teaches, suggests ordiscloses any such invention. Further, to the extent that any meaning ordefinition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed is:
 1. A composition for providing a film on keratinfibres, the composition comprising: (a) an aminosilicone polymer,wherein the aminosilicone polymer comprises a polydimethylsiloxanepolymer having graft amino groups, wherein the aminosilicone polymer hasthe following formula:

wherein x′ and y′ are positive integers, such that a weight averagemolecular weight of the aminosilicone polymer is from 10.000 Dalton to60.000 Dalton and the aminosilicone polymer is in a range of from about0.1% to about 3% by total weight of the composition; (b) an MQ siliconeresin having a weight average molecular weight of from about 1,000Dalton to about 10,000 Dalton and in a range of from about 0.1% to about18% of the composition; (c) an ether of a water-soluble polyhydricalcohol, wherein the ether is chosen from ethylene glycol monohexylether, and a mixture of diethyleneglycol monobutylether and ethyleneglycol monohexyl ether in a range of from about 0.01 wt % to about 20 wt% of the composition; (d) a thickening system in a range of from about0.5% to about 10% by total weight of the composition, the systemcomprising: a deposition enhancer present in a range of from about 0.01%to about 5% of the composition, wherein the deposition enhancer is ahydrophilic and non-ionic polymer, and wherein the deposition enhancerhas a weight average molecular weight of at least about 300,000 Daltonto about 7,500,000 Dalton; a thickening polymer in a range of from about0.01% to about 5% by total weight of the composition, wherein thethickening polymer is a cationic thickening polymer, comprising2-methacryloxyethyltrimethylammonium chloride (Polyquaternium-37); (e)one or more coloured materials or one or more pigments in a range offrom about 1% to about 10% of the composition and having a D₅₀ particlediameter in a range of from about 5 μm to about 60 μm; (f) water; (g)2-phenoxyethanol and/or phenylmethanol ranging from 0.5% to 5% of thecomposition; wherein the composition is free of esters ofparahydroxybenzoic acid; and wherein the composition is free ofisothiazolinone compounds, wherein a pH of the composition is from about3.0 to about 5.0.
 2. The composition of claim 1, wherein the compositioncomprises one or more coloured materials, wherein the one or morecoloured materials is selected from the group consisting of: colouredfibres, coloured beads, coloured particles such as nano-particles,coloured polymers comprising covalently attached dyes, particles havingdiffraction properties, and combinations thereof.
 3. The composition ofclaim 1, wherein the composition has a pH, wherein the pH of thecomposition is from about 3 5 to about 4.5.
 4. The composition of claim1, wherein the composition comprises from about 0.5% to about 2% of thethickening system, by total weight of the composition.
 5. Thecomposition of claim 1, wherein the thickening system further comprisesa hydroxyethyl cellulose.
 6. The composition of claim 1, wherein thecomposition has a viscosity of from about 50 mPa·s to about 1000 mPa·s,wherein the viscosity is measured at about 25° C.
 7. The composition ofclaim 1, wherein the aminosilicone polymer has a weight averagemolecular weight of from about 20,000 Dalton to about 40,000 Dalton. 8.The composition of claim 1, wherein the deposition enhancer conforms tothe formula H(OCH₂CH₂)_(m)OH wherein n has an average value of fromabout 40,000 to about 50,000.
 9. The composition of claim 1, wherein MQsilicone is in a range of from about 0.1% to about 10% of thecomposition.
 10. The composition of claim 1, wherein MQ silicone is in arange of from about 1% to about 5% of the composition.
 11. Thecomposition of claim 1, wherein MQ silicone is in a range of from about2% to about 4% of the composition.
 12. A kit comprising: the compositionof claim 1; an applicator.
 13. The composition of claim 1, furthercomprising one or more radical scavengers.
 14. The composition of claim13, wherein the one or more radical scavengers comprise an alkanolamine,an amino sugar, an amino acid, or mixtures thereof.
 15. The compositionof claim 1, further comprising one or more chelants.
 16. The compositionof claim 15, wherein the one or more chelants comprise histidine,ethylenediamine tetraacetic acid, diamine-N,N′-dipolyacid, monoaminemonoamide-N,N′-dipolyacid, andN,N′-bis(2-hydroxybenzyl)ethylenediamine-N,N′-diacetic acid chelants,carboxylic acids, phosphonic acids, polyphosphoric acids, salts andderivatives thereof or mixtures thereof.
 17. A method for providing afilm comprising one or more pigments or one or more coloured materialsonto keratin fibres, the method comprising applying the composition ofclaim 1 onto keratin fibres and allowing the keratin fibres to dry ordrying them.